Alkaline electrolysers are a type of electrolyser used for hydrogen production through the electrolysis of water. They utilize an alkaline solution, typically potassium hydroxide (KOH) or sodium hydroxide (NaOH), as the electrolyte. Alkaline electrolysers are one of the oldest and most widely used technologies for hydrogen production due to their robustness and cost-effectiveness.

How Alkaline Electrolysers Work

1. Electrolyte: An alkaline electrolyser uses an aqueous alkaline solution as the electrolyte. This solution facilitates the movement of ions between the electrodes.
2. Electrodes: The electrolyser consists of two electrodes—an anode and a cathode—separated by the alkaline electrolyte.

○       Anode Reaction: At the anode, water is oxidized to form oxygen gas, protons, and electrons.

○       Cathode Reaction: At the cathode, the protons combine with electrons to form hydrogen gas.

3. Overall Reaction: The overall reaction in an alkaline electrolyser is the splitting of water into hydrogen and oxygen gases.

Advantages of Alkaline Electrolysers

1. Cost-Effectiveness: Alkaline electrolysers are generally less expensive compared to other types of electrolysers, such as PEM (Proton Exchange Membrane) electrolysers, primarily due to their simpler construction and use of less costly materials.
2. Mature Technology: Alkaline electrolysis is a well-established technology with a long history of use in industrial applications. This maturity translates into proven reliability and performance.
3. Durability and Longevity: Alkaline electrolysers are known for their durability and long operational life. They can operate for extended periods with minimal maintenance.
4. High Efficiency: They offer relatively high efficiency for large-scale hydrogen production, particularly when operating at optimal conditions.
5. Scalability: Alkaline electrolysers can be easily scaled up to meet high hydrogen production demands, making them suitable for both small and large-scale applications.
6. Low Operating Pressure: Alkaline electrolysers operate at lower pressures compared to some other electrolyser technologies, which can reduce the need for additional compression equipment.

Applications of Alkaline Electrolysers

1. Industrial Hydrogen Production: Alkaline electrolysers are widely used in industrial settings for the production of hydrogen gas. This hydrogen is used in various processes, including ammonia production, methanol synthesis, and petroleum refining.
2. Energy Storage: In energy storage systems, alkaline electrolysers convert excess electrical energy from renewable sources into hydrogen, which can be stored and later used to generate electricity through fuel cells or combustion.
3. Hydrogen Fueling Stations: Alkaline electrolysers are used in hydrogen fueling stations to produce hydrogen on-site for fuel cell vehicles, contributing to the development of a hydrogen economy.
4. Chemical Production: The hydrogen produced by alkaline electrolysers is used in the synthesis of chemicals such as hydrogen chloride, hydrazine, and other compounds.
5. Waste Water Treatment: Alkaline electrolysis can be used in advanced waste water treatment processes to produce hydrogen and oxygen, which can aid in the treatment of organic contaminants.
6. Renewable Energy Integration: Alkaline electrolysers are used to integrate renewable energy sources, such as solar and wind, by converting excess energy into hydrogen, which can be stored and used as a clean energy source.

Challenges and Considerations

1. Lower Efficiency at Small Scale: Alkaline electrolysers may have lower efficiency at smaller scales compared to some other technologies, which can impact their suitability for certain applications.
2. Corrosion and Maintenance: The alkaline environment can cause corrosion of materials and components, leading to increased maintenance requirements over time.
3. Slower Start-Up: Alkaline electrolysers can have slower start-up times compared to some other types, which may affect their responsiveness in dynamic applications.

Conclusion

Alkaline electrolysers are a reliable and cost-effective technology for hydrogen production, known for their durability, efficiency, and scalability. Their use in various industrial applications, energy storage systems, and renewable energy integration underscores their importance in advancing hydrogen technology. Despite some challenges, their well-established technology and ability to produce high-purity hydrogen make them a valuable component in the transition to a sustainable energy future.