Hydrogen electrolysers are devices that use electricity to split water into hydrogen and oxygen, playing a pivotal role in producing green hydrogen, a key component in the transition to a sustainable energy future. Unlike traditional hydrogen production methods that rely on fossil fuels, electrolysers can generate hydrogen with zero emissions when powered by renewable energy. In this article, we will explore how hydrogen electrolysers work, their different types, and the role they play in a cleaner, decarbonized world.

How Do Hydrogen Electrolysers Work?

At the core of a hydrogen electrolyser is the process of electrolysis, which involves passing an electric current through water (H₂O) to separate it into its component gases: hydrogen (H₂) and oxygen (O₂). The overall chemical reaction can be represented as:

The hydrogen produced can be stored and later used as a clean fuel for a variety of applications, including transportation, power generation, and industrial processes. The oxygen is often released as a byproduct, though it can also be captured for use in other industries.

Types of Hydrogen Electrolysers

There are several different types of electrolysers, each with its own set of advantages, challenges, and applications. The three main types are:

1. Alkaline Electrolysers (AEL)
2. Proton Exchange Membrane (PEM) Electrolysers
3. Solid Oxide Electrolysers (SOE)

Let’s dive into each one in detail.

1. Alkaline Electrolysers (AEL)

Alkaline electrolysers are the most mature and widely used electrolysis technology. They use a liquid alkaline electrolyte, typically potassium hydroxide (KOH), to conduct the electric current between two electrodes.

●       Advantages: AELs are known for their reliability and long operational life. They are relatively low-cost compared to other types of electrolysers and can handle large-scale hydrogen production.

●       Challenges: Alkaline electrolysers operate at lower current densities, meaning they are less efficient than some newer technologies. Additionally, they are slower to respond to fluctuations in power supply, making them less compatible with intermittent renewable energy sources like wind and solar.

2. Proton Exchange Membrane (PEM) Electrolysers

PEM electrolysers use a solid polymer electrolyte to conduct protons from the anode to the cathode during the electrolysis process. This newer technology is quickly gaining traction due to its high efficiency and operational flexibility.

●       Advantages: PEM electrolysers are highly responsive to changes in electricity supply, making them ideal for pairing with renewable energy sources that produce variable power. They operate at higher current densities, allowing for more compact and efficient systems.

●       Challenges: The materials used in PEM electrolysers, such as platinum and iridium, are expensive, which raises the cost of these systems. However, ongoing research aims to reduce material costs while maintaining performance.

3. Solid Oxide Electrolysers (SOE)

Solid oxide electrolysers operate at high temperatures (usually between 700°C and 1,000°C) and use a ceramic electrolyte to conduct oxygen ions. This type of electrolyser is still in the research and development phase but holds significant promise for large-scale hydrogen production.

●       Advantages: SOEs have the potential to be the most efficient of all electrolyser types, as high operating temperatures reduce the amount of electricity needed to split water. They can also be integrated with industrial processes that already generate high-temperature heat, improving overall system efficiency.

Challenges: The main drawback of SOEs is their high operating temperature, which leads to complex material challenges and durability issues. Developing materials that can withstand such extreme conditions for long periods is a significant engineering